Product ID:METHYL ISOBUTYL KETONE,SPC 19050
MSDS Date:10/30/1996
FSC:6810
NIIN:00-281-2761
MSDS Number: CGLRV

EASTMAN CHEM PRODUCTS A SUB OF EASTMAN KODAK CO

WILCOX DR AND LINCOLN ST
KINGSPORT, TN 37662
US

Emergency Phone: 800-EASTMAN/800-424-9300(CHEMTREC)

Info Phone: 423-229-2000

Cage: 74364

PHASAR INC

JENSEN BEACH, FL 34957 US

Telephone: 800-422-7747

Cage: 0WHD7

METHYL ISOBUTYL KETONE (HEXONE) (SARA 313) (CERCLA)

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 100%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM/75 STEL; 9596

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50 (ORAL, RAT) 1600-3200 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS,
RESPIRATORY & GI TRACTS. ACUTE- EXPECTED TO BE A LOW INGESTION
HAZARD. MAY CAUSE EYE IRRITATION. PROLONGED/REPEATED SKIN CONTACT
MAY CAUSE DEFATTING. INHALATION OF HIGH V APOR CONCENTRATIONS MAY
CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. CHRONIC- LIVER & KIDNEY
EFFECTS IN MALE RATS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, DROWSINESS,
NAUSEA, VOMITING, TEARING, DEFATTING OF SKIN, CRACKING
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS OR IMPAIRED CENTRAL NERVOUS SYSTEM OR
RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS
PRODUCT.

First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:MOVE TO FRESH
AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:IMMEDIATELY FLUSH WITH
WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. SKIN:WASH WITH SOAP &
WATER. ORAL:DO NOT INDUCE VOMITING. ASPIRATION HAZARD.SEEK MEDICAL
ATTENTION. IF VOMITING OCCURS, KEEP HEAD BELOW HIPS. DO NOT GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.

Flash Point Method:TCC
Flash Point:60.0F,15.6C
Autoignition Temp:Autoignition Temp Text:829F
Lower Limits:1.2
Upper Limits:8.0
Extinguishing Media:USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE. WATER MAY
BE INEFFECTIVE BUT SHOULD BE USED TO COOL FIRE-EXPOSED CONTAINERS.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK.
CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES
OF IGNITION. VENTILATE AREA. REMOVE SPILL WITH NON-SPARKING
PUMPS/NON-FLAMMABLE ABSORBENT SUCH AS SAND. PLACE IN CONTAINER FOR
REUSE/RECYCLING OR DISPOSAL. PREVENT LIQUID FROM ENTERING SEWERS,
WATERWAYS.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:STORE IN COOL, VENTILATED AREA, AWAY
FROM IGNITION SOURCES & INCOMPATIBLES. KEEP CONTAINER TIGHTLY
CLOSED. TEST FOR PEROXIDE IN BULK QUANTITIES.
Other Precautions:WARNING! FLAMMABLE. "EMPTY" CONTAINERS RETAIN RESIDUE
AND CAN BE DANGEROUS. FOLLOW LABEL INSTRUCTIONS. KEEP OUT OF REACH
OF CHILDREN. AVOID BREATHING VAPORS. DO NOT GET IN EYE, ON SKIN OR
ON CLOTHING. AVOID DIRECT SUNLIGHT.

Respiratory Protection:IF TLV IS EXCEEDED OR FOR SYMPTOMS OF OVER
EXPOSURE, WEAR NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR OR SUPPLIED
AIR RESPIRATOR. IN EMERGENCY, WEAR A NIOSH-APPROVED
POSITIVE-PRESSURE SELF-CONTAINED BREAT HING APPARATUS.
Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:RUBBER, NEOPRENE FOR REPEATED CONTACT
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLESS
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWERS SHOULD BE
AVAILABLE IN THE IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE.
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH AFTER HANDLING AND BEFORE EATING OR
DRINKING.
Supplemental Safety and Health

HCC:F2
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=117.C, 242.6F
Melt/Freeze Pt:=-85.C, -121.F
Vapor Pres:15 @ 68F
Vapor Density:3.5
Spec Gravity:0.80
Evaporation Rate & Reference:1.6 (N-BUTYL ACETATE=1)
Solubility in Water:MODERATE
Appearance and Odor:CLEAR, COLORLESS LIQUID - KETONE ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG REDUCING AGENTS, AMINES, ACIDS, BASES,
HALOGENATED MATERIALS
Stability Condition to Avoid:HIGH HEAT, SUNLIGHT, SPARKS, FLAMES, HOT
SURFACES AND OTHER SOURCES OF IGNITION. MAY FORM EXPLOSIVE PEROXIDE
ON CONCEN.
Hazardous Decomposition Products:MAY EMIT CARBON MONOXIDE, CARBON
DIOXIDE.

Waste Disposal Methods:DISPOSE IN AN APPROVED INCINERATOR/CONTRACT WITH
LICENSED CHEMICAL WASTE DISPOSAL SERVICE. DISCHARGE,
TREATMENT/DISPOSAL IS SUBJECT TO FEDERAL, STATE OR LOCAL LAWS
(WASTE CODE D001).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.